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Issue 1, 2014
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Iron catalysed nitrosation of olefins to oximes

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Abstract

Fe(BF4)2·6H2O/2,6-pyridinedicarboxylic acid catalysed nitrosation of a wide variety of substituted styrenes has been developed in the presence of t-BuONO/NaBH4 under H2 pressure (10 bar) in MeOH–H2O (5 : 1) to afford corresponding oximes in good to excellent yields.

Graphical abstract: Iron catalysed nitrosation of olefins to oximes

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Publication details

The article was received on 01 Jul 2013, accepted on 14 Oct 2013 and first published on 14 Oct 2013


Article type: Communication
DOI: 10.1039/C3DT51764K
Citation: Dalton Trans., 2014,43, 38-41
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    Iron catalysed nitrosation of olefins to oximes

    R. Ray, A. D. Chowdhury, D. Maiti and G. K. Lahiri, Dalton Trans., 2014, 43, 38
    DOI: 10.1039/C3DT51764K

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