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Issue 11, 2014
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The first enantiopure lanthanoid cryptate

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Abstract

The first enantiomerically pure 2,2′-bipyridine-based cryptand is reported. Complexation of this macrobicyclic ligand with the trivalent lanthanoidcations Yb and Lu produces enantiomerically and diastereomerically pure cryptates in solution. The Yb cryptate shows near-IR photoluminescence with lifetimes of up to τ = 29.8 μs in CD3OD.

Graphical abstract: The first enantiopure lanthanoid cryptate

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Publication details

The article was received on 16 May 2013, accepted on 26 Jul 2013 and first published on 09 Aug 2013


Article type: Communication
DOI: 10.1039/C3DT51289D
Citation: Dalton Trans., 2014,43, 4238-4241
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    The first enantiopure lanthanoid cryptate

    T. Güden-Silber, C. Doffek, C. Platas-Iglesias and M. Seitz, Dalton Trans., 2014, 43, 4238
    DOI: 10.1039/C3DT51289D

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