Issue 1, 2014
From the journal:

Catalysis Science & Technology

Efficient H2 generation from formic acid using azole complexes in water†

Yuichi Manaka,a   Wan-Hui Wang,*ab   Yuki Suna,a   Hide Kambayashi,a   James T. Muckerman,c   Etsuko Fujitac  and  Yuichiro Himeda*ab  

* Corresponding authors

a National Institute of Advanced Industrial Science and Technology, Tsukuba Central 5-2, 1-1-1 Higashi, Ibaraki, Tsukuba, 305-8565 Japan
E-mail: himeda.y@aist.go.jp, ou-wanhui@aist.go.jp

b JST, ACT-C, 4-1-8 Honcho, Saitama, Kawaguchi, 332-0012 Japan

c Chemistry Department, Brookhaven National Laboratory, Upton, NY 11973-5000, USA

Abstract

Iridium azole-containing complexes are demonstrated to catalyze the dehydrogenation of formic acid into H2–CO2 (1/1) mixtures in aqueous solution in the absence of organic additives, and with a maximum turnover frequency (TOF) of 34 000 h−1 at 80 °C.

Graphical abstract: Efficient H2 generation from formic acid using azole complexes in water

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Article information

DOI
https://doi.org/10.1039/C3CY00830D
Article type
Communication
Submitted
22 Oct 2013
Accepted
22 Oct 2013
First published
23 Oct 2013

Catal. Sci. Technol., 2014,4, 34-37

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Efficient H2 generation from formic acid using azole complexes in water

Y. Manaka, W. Wang, Y. Suna, H. Kambayashi, J. T. Muckerman, E. Fujita and Y. Himeda, Catal. Sci. Technol., 2014, 4, 34 DOI: 10.1039/C3CY00830D

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