Issue 12, 2014

Ethene oligomerization on H-ZSM-5 in relation to ethoxy species

Abstract

The oligomerization of ethene over H-ZSM-5 was studied by infrared (IR) spectroscopy. The possibility of an ethoxy intermediate for ethene oligomerization was investigated. Ethene oligomerization was found to proceed on the basis of a concerted mechanism with plural ethene molecules and not by a stepwise mechanism with an ethoxy intermediate.

Graphical abstract: Ethene oligomerization on H-ZSM-5 in relation to ethoxy species

Article information

Article type
Communication
Submitted
08 Aug 2014
Accepted
10 Sep 2014
First published
19 Sep 2014

Catal. Sci. Technol., 2014,4, 4193-4195

Author version available

Ethene oligomerization on H-ZSM-5 in relation to ethoxy species

H. Yamazaki, T. Yokoi, T. Tatsumi and J. N. Kondo, Catal. Sci. Technol., 2014, 4, 4193 DOI: 10.1039/C4CY01028K

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