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Issue 17, 2014
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Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates

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Abstract

This tutorial review highlights the organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium/azolium enolates. The generation and synthetic utility of these powerful intermediates is highlighted through their application in various methodologies including aldol-lactonisations, Michael-lactonisations/lactamisations and [2,3]-rearrangements.

Graphical abstract: Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates

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Publication details

The article was received on 23 Jan 2014 and first published on 28 May 2014


Article type: Tutorial Review
DOI: 10.1039/C4CS00042K
Citation: Chem. Soc. Rev., 2014,43, 6214-6226
  • Open access: Creative Commons BY license
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    Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates

    L. C. Morrill and A. D. Smith, Chem. Soc. Rev., 2014, 43, 6214
    DOI: 10.1039/C4CS00042K

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