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Issue 44, 2014
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Influence of intermolecular interactions on spectroscopic characteristics of metal nanoparticles and their composites

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Abstract

In this paper we investigate the possibility to apply the concepts of non-specific intermolecular interactions and dispersive local field effect approach for study of the influence of interactions of metal nanoparticles with matrix molecules on the spectral characteristics of composites. The effect of intermolecular (interparticle) interactions and the influence of the dielectric environment on the peak position of the plasmon resonance band of colloidal solutions and thin films formed from noble metal nanostructures is determined. Simulated and experimental absorption spectra obtained for a colloidal solution of silver and gold nanoparticles, of various shapes and sizes in water and glycerol, are in good agreement.

Graphical abstract: Influence of intermolecular interactions on spectroscopic characteristics of metal nanoparticles and their composites

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Publication details

The article was received on 14 Aug 2014, accepted on 28 Sep 2014 and first published on 01 Oct 2014


Article type: Paper
DOI: 10.1039/C4CP03639E
Author version available: Download Author version (PDF)
Citation: Phys. Chem. Chem. Phys., 2014,16, 24536-24548
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    Influence of intermolecular interactions on spectroscopic characteristics of metal nanoparticles and their composites

    I. I. Shaganov, T. S. Perova, M. V. Mukhina, I. V. Martynenko, A. V. Baranov, A. V. Fedorov, V. Gerard and Y. K. Gun'ko, Phys. Chem. Chem. Phys., 2014, 16, 24536
    DOI: 10.1039/C4CP03639E

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