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Issue 18, 2014
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Ceria co-doping: synergistic or average effect?

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Ceria (CeO2) co-doping has been suggested as a means to achieve ionic conductivities that are significantly higher than those in singly doped systems. Rekindled interest in this topic over the last decade has given rise to claims of much improved performance. The present study makes use of computer simulations to investigate the bulk ionic conductivity of rare earth (RE) doped ceria, where RE = Sc, Gd, Sm, Nd and La. The results from the singly doped systems are compared to those from ceria co-doped with Nd/Sm and Sc/La. The pattern that emerges from the conductivity data is consistent with the dominance of local lattice strains from individual defects, rather than the synergistic co-doping effect reported recently, and as a result, no enhancement in the conductivity of co-doped samples is observed.

Graphical abstract: Ceria co-doping: synergistic or average effect?

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Publication details

The article was received on 27 Feb 2014, accepted on 28 Feb 2014 and first published on 28 Feb 2014

Article type: Paper
DOI: 10.1039/C4CP00856A
Author version available: Download Author version (PDF)
Citation: Phys. Chem. Chem. Phys., 2014,16, 8320-8331
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    Ceria co-doping: synergistic or average effect?

    M. Burbano, S. Nadin, D. Marrocchelli, M. Salanne and G. W. Watson, Phys. Chem. Chem. Phys., 2014, 16, 8320
    DOI: 10.1039/C4CP00856A

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