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Issue 20, 2014
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Syntheses of two coordination polymers with rutile-type topology and the single-crystal-to-single-crystal transformation of Mg(II) complex induced by methanol

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Abstract

Two isomorphous 3D frameworks with rutile topology based on isonicotinate, [Mn(IN)2]·H2O (1) and [Mg(IN)2]·H2O (2), were prepared. Compound 1 shows excellent stability in alcohols, while compound 2 reveals a rare single-crystal-to-single-crystal transformation from a 3D structure to a mononuclear molecule of [Mg(IN)2(CH3OH)4] (3) by soaking in methanol.

Graphical abstract: Syntheses of two coordination polymers with rutile-type topology and the single-crystal-to-single-crystal transformation of Mg(ii) complex induced by methanol

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Publication details

The article was received on 31 Dec 2013, accepted on 16 Feb 2014 and first published on 07 Apr 2014


Article type: Paper
DOI: 10.1039/C3CE42660B
Citation: CrystEngComm, 2014,16, 4210-4214
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    Syntheses of two coordination polymers with rutile-type topology and the single-crystal-to-single-crystal transformation of Mg(II) complex induced by methanol

    Y. He, J. Guo, H. Zhang, J. Yang, Y. Liu and J. Ma, CrystEngComm, 2014, 16, 4210
    DOI: 10.1039/C3CE42660B

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