Issue 43, 2014
From the journal:

CrystEngComm

Metal-free 1,3-dipolar cycloaddition polymerization via prearrangement of azide and alkyne in the solid state†

Xiao Meng,a   Hao Chen,a   Shu Xua  and  Yuguo Ma*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences (BNLMS), Center for Soft Matter Science and Engineering, Key Lab of Polymer Chemistry & Physics of Ministry of Education, College of Chemistry, Peking University, Beijing, China
E-mail: ygma@pku.edu.cn
Fax: +86 10 6275 1708
Tel: +86 10 6275 6660

Abstract

Metal-free 1,3-dipolar cycloaddition polymerization with controlled regioselectivity is achieved by pre-organizing azide and terminal alkyne functional groups in the solid state. Soluble polymers are obtained with monomers containing flexible tri- and tetra-ethylene glycol linkers.

Graphical abstract: Metal-free 1,3-dipolar cycloaddition polymerization via prearrangement of azide and alkyne in the solid state

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Article information

DOI
https://doi.org/10.1039/C4CE01690D
Article type
Communication
Submitted
15 Aug 2014
Accepted
12 Sep 2014
First published
26 Sep 2014

CrystEngComm, 2014,16, 9983-9986

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Metal-free 1,3-dipolar cycloaddition polymerization via prearrangement of azide and alkyne in the solid state

X. Meng, H. Chen, S. Xu and Y. Ma, CrystEngComm, 2014, 16, 9983 DOI: 10.1039/C4CE01690D

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