Issue 37, 2014

The crystallographic observation of mesitylene–mesitylene and mesitylene–CH2Cl2–mesitylene adducts trapped in an irregular cavity

Abstract

We report two crystals and one gel formed by a chiral Mo(VI) complex. The particular accumulation of complex molecules creates inert irregular cavities for trapping a solvent adduct. The sp3-CH–π interaction models of mesitylene–mesitylene and mesitylene–CH2Cl2–mesitylene adducts in an irregular accumulation environment are directly observed.

Graphical abstract: The crystallographic observation of mesitylene–mesitylene and mesitylene–CH2Cl2–mesitylene adducts trapped in an irregular cavity

Supplementary files

Article information

Article type
Communication
Submitted
15 Jul 2014
Accepted
24 Jul 2014
First published
24 Jul 2014

CrystEngComm, 2014,16, 8652-8655

Author version available

The crystallographic observation of mesitylene–mesitylene and mesitylene–CH2Cl2–mesitylene adducts trapped in an irregular cavity

Y. Chen, L. Ma, Z. Bian, R. Jin, C. Kang, Z. Li, X. Gao, F. Han, X. Qiu and L. Gao, CrystEngComm, 2014, 16, 8652 DOI: 10.1039/C4CE01403K

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