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Issue 37, 2014
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Two porous metal–organic frameworks containing zinc–calcium clusters and calcium cluster chains

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Abstract

A two-dimensional metal–organic framework (MOF) containing both Zn(II) and Ca(II) centres and a three-dimensional MOF containing only Ca(II) centres have the largest surface areas (BET 1560 and 914 m2 g−1, respectively) among the reported Ca-based MOFs and also exhibit high gas uptake up to 1 bar for H2 at 77 K and CO2 at 298 K.

Graphical abstract: Two porous metal–organic frameworks containing zinc–calcium clusters and calcium cluster chains

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Publication details

The article was received on 17 Jun 2014, accepted on 28 Jul 2014 and first published on 29 Jul 2014


Article type: Communication
DOI: 10.1039/C4CE01237B
Author version available: Download Author version (PDF)
Citation: CrystEngComm, 2014,16, 8664-8668
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    Two porous metal–organic frameworks containing zinc–calcium clusters and calcium cluster chains

    K. Noh, N. Ko, H. J. Park, S. Park and J. Kim, CrystEngComm, 2014, 16, 8664
    DOI: 10.1039/C4CE01237B

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