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Issue 35, 2014
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Reversible recrystallization process of copper and silver thioacetamide–halide coordination polymers and their basic building blocks

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Abstract

Three-dimensional [CuX(TAA)]n (X = Br (1), I (2)) and bi-dimensional [AgX(TAA)]n (X = Cl (3), Br (4)) coordination polymers have been isolated by the direct synthesis from copper(I) and silver(I) halides and thioacetamide (TAA). These are multifunctional materials showing electrical conductivity (values at room temperature ranging from 7 × 10−6 to 2 × 10−9 S cm−1) and luminescence in the blue region. The unusual solubility of 1–4 in different solvents and the recrystallization process observed for 1 and 2 in acetonitrile and for 3 and 4 in pyridine have been measured. We show preliminary results of the processability of 2 on glass for the production of organized thin films. These results are very attractive for the processability of coordination polymers in materials science and nanoscience.

Graphical abstract: Reversible recrystallization process of copper and silver thioacetamide–halide coordination polymers and their basic building blocks

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Publication details

The article was received on 07 Mar 2014, accepted on 25 Apr 2014 and first published on 25 Apr 2014


Article type: Paper
DOI: 10.1039/C4CE00480A
Author version available: Download Author version (PDF)
Citation: CrystEngComm, 2014,16, 8224-8231
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    Reversible recrystallization process of copper and silver thioacetamide–halide coordination polymers and their basic building blocks

    J. Troyano, J. Perles, P. Amo-Ochoa, J. I. Martínez, F. Zamora and S. Delgado, CrystEngComm, 2014, 16, 8224
    DOI: 10.1039/C4CE00480A

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