Issue 94, 2014
From the journal:

Chemical Communications

Cerium tetrakis(diisopropylamide) – a useful precursor for cerium(iv) chemistry†

David Schneider,a   Tatiana Spallek,a   Cäcilia Maichle-Mössmer,a   Karl W. Törnroosb  and  Reiner Anwander*a  

* Corresponding authors

a Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany
E-mail: reiner.anwander@uni-tuebingen.de

b University of Bergen, Department of Chemistry, Bergen, Norway

Abstract

Homoleptic cerium(IV) diisopropylamide was synthesized via oxidation of ate complex Ce(NiPr2)4Li(thf) with trityl chloride or hexachloroethane. Due to its ready accessibility, and high pKa value of the proligand HNiPr2, Ce(NiPr2)4 features a promising candidate for protonolysis reactions, as shown for the synthesis of dimeric cerium(IV) tetrakis(1,1,3,3-N,N,N′,N′-tetramethylguanidinate).

Graphical abstract: Cerium tetrakis(diisopropylamide) – a useful precursor for cerium(iv) chemistry

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC06228K
Article type
Communication
Submitted
08 Aug 2014
Accepted
07 Oct 2014
First published
08 Oct 2014

Chem. Commun., 2014,50, 14763-14766

Permissions

Request permissions

Cerium tetrakis(diisopropylamide) – a useful precursor for cerium(IV) chemistry

D. Schneider, T. Spallek, C. Maichle-Mössmer, K. W. Törnroos and R. Anwander, Chem. Commun., 2014, 50, 14763 DOI: 10.1039/C4CC06228K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements