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Issue 92, 2014
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Direct carboxylation of simple arenes with CO2 through a rhodium-catalyzed C–H bond activation

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Abstract

Direct carboxylation of simple arenes under atmospheric pressure of CO2 is achieved through a rhodium-catalyzed C–H bond activation without the assistance of a directing group. Various arenes such as benzene, toluene, xylene, electron-rich or electron-deficient benzene derivatives, and heteroaromatics are directly carboxylated with high TONs.

Graphical abstract: Direct carboxylation of simple arenes with CO2 through a rhodium-catalyzed C–H bond activation

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Publication details

The article was received on 07 Aug 2014, accepted on 23 Sep 2014 and first published on 23 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC06188H
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 14360-14363
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    Direct carboxylation of simple arenes with CO2 through a rhodium-catalyzed C–H bond activation

    T. Suga, H. Mizuno, J. Takaya and N. Iwasawa, Chem. Commun., 2014, 50, 14360
    DOI: 10.1039/C4CC06188H

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