Efficient molecular recognition based on nonspecific van der Waals interaction at the solid/liquid interface

Lili Cao; Lirong Xu; Dahui Zhao; Kazukuni Tahara; Yoshito Tobe; Steven De Feyter; Shengbin Lei

doi:10.1039/C4CC03658A

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Efficient molecular recognition based on nonspecific van der Waals interaction at the solid/liquid interface†

Lili Cao,^a Lirong Xu,^a Dahui Zhao,^b Kazukuni Tahara,^c Yoshito Tobe,^c Steven De Feyter^d and Shengbin Lei*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Microsystems and Microstructures Manufacturing, Ministry of Education, Harbin Institute of Technology, Harbin, People's Republic of China
E-mail: leisb@hit.edu.cn

^b Department of Applied Chemistry and the Key Laboratory of Polymer Chemistry and Physics of the Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China

^c Division of Frontier Materials Science, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

^d Division of Molecular and Nanomaterials, Department of Chemistry, KU Leuven – University of Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

Abstract

A highly efficient recognition phenomenon was observed between alkoxylated arylene–ethynylene macrocycles bearing identical side chains but different core size, which is based on van der Waals interactions between alkoxy chains. The ratio of both molecules and the environment of each molecule have been statistically analyzed to quantify the recognition efficiency.

This article is part of the themed collection: Scanning Probe Studies of Molecular Systems

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Article information

DOI: https://doi.org/10.1039/C4CC03658A
Article type: Communication
Submitted: 14 May 2014
Accepted: 14 Aug 2014
First published: 14 Aug 2014

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Chem. Commun., 2014,50, 11946-11949

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Efficient molecular recognition based on nonspecific van der Waals interaction at the solid/liquid interface

L. Cao, L. Xu, D. Zhao, K. Tahara, Y. Tobe, S. De Feyter and S. Lei, Chem. Commun., 2014, 50, 11946 DOI: 10.1039/C4CC03658A

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Chemical Communications

Efficient molecular recognition based on nonspecific van der Waals interaction at the solid/liquid interface†

Abstract

Supplementary files

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Efficient molecular recognition based on nonspecific van der Waals interaction at the solid/liquid interface

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