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Issue 53, 2014
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Direct evidence of Lowenstein's rule violation in swelling high-charge micas

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Abstract

The structure of high-charged micas, Na-n-micas (n = 2 and 4), a family of synthetic silicates with a wide range of applications, was investigated through the use of 17O solid-state NMR at natural abundance in order to preserve quantitative spectral information. The use of a very high-field and highly sensitive probehead, together with 17O NMR literature data allowed for the detection of an isolated signal at 26 ppm, assigned partially to AlOAl, as evidence of the violation of Lowenstein's rule for Na-4-mica.

Graphical abstract: Direct evidence of Lowenstein's rule violation in swelling high-charge micas

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Publication details

The article was received on 04 Mar 2014, accepted on 08 May 2014 and first published on 08 May 2014


Article type: Communication
DOI: 10.1039/C4CC01632G
Citation: Chem. Commun., 2014,50, 6984-6986
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    Direct evidence of Lowenstein's rule violation in swelling high-charge micas

    E. Pavón, F. J. Osuna, M. D. Alba and L. Delevoye, Chem. Commun., 2014, 50, 6984
    DOI: 10.1039/C4CC01632G

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