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Issue 45, 2014
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A gold-catalysed fully intermolecular oxidation and sulfur-ylide formation sequence on ynamides

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Abstract

An efficient C–O, C–S and C–C bond-forming sequence leads to functionalised compounds bearing sulfur-substituted quaternary carbons. Ynamides are employed as diazo-equivalents to access the [2,3]-sigmatropic rearrangements of allyl sulfonium ylides by a three-component chemoselective oxidation and intermolecular ylide formation.

Graphical abstract: A gold-catalysed fully intermolecular oxidation and sulfur-ylide formation sequence on ynamides

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Publication details

The article was received on 10 Feb 2014, accepted on 16 Apr 2014 and first published on 16 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC01059K
Citation: Chem. Commun., 2014,50, 6001-6004
  • Open access: Creative Commons BY license
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    A gold-catalysed fully intermolecular oxidation and sulfur-ylide formation sequence on ynamides

    M. D. Santos and P. W. Davies, Chem. Commun., 2014, 50, 6001
    DOI: 10.1039/C4CC01059K

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