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Issue 30, 2014
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Oxidative addition of ether O-methyl bonds at a Pt(0) centre

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Abstract

Pt(PCyp3)2 (Cyp = cyclopentyl) undergoes C–O oxidative addition with 2,3,5,6-tetrafluoro-4-methoxypyridine, pentafluoroanisole, 2,3,5,6-tetrafluoroanisole and 2,3,6-trifluoroanisole yielding platinum methyl derivatives. The reactions occur in preference to C–H or C–F activation.

Graphical abstract: Oxidative addition of ether O-methyl bonds at a Pt(0) centre

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Publication details

The article was received on 31 Jan 2014, accepted on 06 Feb 2014 and first published on 06 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00853G
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 3914-3917
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    Oxidative addition of ether O-methyl bonds at a Pt(0) centre

    N. A. Jasim, R. N. Perutz, B. Procacci and A. C. Whitwood, Chem. Commun., 2014, 50, 3914
    DOI: 10.1039/C4CC00853G

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