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Issue 34, 2014
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Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine

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Abstract

Cofacial Fe2, Co2, and Ni2 complexes supported by a para-terphenyl diphosphine ligand were prepared. Central arene deplanarization and a μ2:(η33) coordination mode suggest partial bisallyl character in the Fe2 and Co2 complexes. An oxidation induced shift in Fe2–arene binding highlights the non-innocent nature of the arene ligand.

Graphical abstract: Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine

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Publication details

The article was received on 30 Jan 2014, accepted on 28 Feb 2014 and first published on 03 Mar 2014


Article type: Communication
DOI: 10.1039/C4CC00838C
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 4427-4429
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    Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine

    K. T. Horak, A. Velian, M. W. Day and T. Agapie, Chem. Commun., 2014, 50, 4427
    DOI: 10.1039/C4CC00838C

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