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Issue 28, 2014
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Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

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Abstract

X-ray crystallography showcases the distinct self-association and hydrogen-bonding patterns of organic silanediols, R2Si(OH)2, with bifunctional heterocycles for supramolecular assembly. Diffusion-ordered spectroscopy (DOSY) studies identify the dominant hydrogen-bonding patterns and structures in solution, which correlate with solid-state patterns at high concentrations.

Graphical abstract: Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

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Publication details

The article was received on 25 Jan 2014, accepted on 19 Feb 2014 and first published on 19 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00672K
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 3738-3740
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    Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

    N. T. Tran, S. O. Wilson and A. K. Franz, Chem. Commun., 2014, 50, 3738
    DOI: 10.1039/C4CC00672K

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