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Issue 41, 2014
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Sterically controlled self-assembly of tetrahedral M6L4 cages via cationic N-donor ligands

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Abstract

Tripodal cationic N-donor ligands exhibit sterically controlled self-assembly of tetrahedral M6L4 coordination cages that promote selective anion encapsulation (PF6 > OTf) in the solid state. The described method is a potential template for stepwise assembly of hetero-ligand coordination cages and polymers.

Graphical abstract: Sterically controlled self-assembly of tetrahedral M6L4 cages via cationic N-donor ligands

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Publication details

The article was received on 20 Dec 2013, accepted on 25 Mar 2014 and first published on 25 Mar 2014


Article type: Communication
DOI: 10.1039/C3CC49663E
Citation: Chem. Commun., 2014,50, 5469-5472
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    Sterically controlled self-assembly of tetrahedral M6L4 cages via cationic N-donor ligands

    A. Peuronen, S. Forsblom and M. Lahtinen, Chem. Commun., 2014, 50, 5469
    DOI: 10.1039/C3CC49663E

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