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Issue 15, 2014
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Efficient photocatalytic hydrogen generation from water by a cationic cobalt(II) porphyrin

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Abstract

Efficient photocatalytic hydrogen evolution is obtained from 1 M phosphate buffer at pH 7 in the presence of a Ru(bpy)32+ sensitizer, an ascorbic acid sacrificial donor, and a water-soluble Co(II) porphyrin catalyst. Spectroscopic investigation of the system by stationary and time-resolved techniques enables a complete characterization of the photoinduced dynamics.

Graphical abstract: Efficient photocatalytic hydrogen generation from water by a cationic cobalt(ii) porphyrin

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Publication details

The article was received on 20 Nov 2013, accepted on 17 Dec 2013 and first published on 18 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC48882A
Citation: Chem. Commun., 2014,50, 1842-1844
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    Efficient photocatalytic hydrogen generation from water by a cationic cobalt(II) porphyrin

    M. Natali, A. Luisa, E. Iengo and F. Scandola, Chem. Commun., 2014, 50, 1842
    DOI: 10.1039/C3CC48882A

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