Jump to main content
Jump to site search

Issue 31, 2014
Previous Article Next Article

X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Author affiliations

Abstract

A cyanide-bridged tetranuclear Fe–Co complex showed electron-transfer-coupled spin transitions induced by X-ray irradiation. Single crystal X-ray diffraction measurements and X-ray absorption spectroscopy revealed that the X-ray-induced phase transition ratio was significantly altered by the selective excitation of the metal ions.

Graphical abstract: X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Nov 2013, accepted on 17 Jan 2014 and first published on 20 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC48820A
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 4050-4052
  •   Request permissions

    X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

    Y. Sekine, M. Nihei, R. Kumai, H. Nakao, Y. Murakami and H. Oshio, Chem. Commun., 2014, 50, 4050
    DOI: 10.1039/C3CC48820A

Search articles by author

Spotlight

Advertisements