Issue 18, 2014
From the journal:

Chemical Communications

A direct, versatile route to functionalized trialkoxysilanes†‡

Béatrice Quiclet-Sire,*a   Yuuki Yanagisawa§a  and  Samir Z. Zard*a  

* Corresponding authors

a Laboratoire de Synthèse Organique, CNRS UMR 7652, Ecole Polytechnique, F-91128 Palaiseau, France
E-mail: zard@poly.polytechnique.fr
Fax: +33 169335972
Tel: +33 169335971

Abstract

The peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkoxy vinylsilanes leads to functionalized trialkoxysilanes. Prior addition of the dithiocarbonates to an alkene before reaction with the vinylsilane can be used to increase the complexity of the final product.

Graphical abstract: A direct, versatile route to functionalized trialkoxysilanes

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Article information

DOI
https://doi.org/10.1039/C3CC48570F
Article type
Communication
Submitted
09 Nov 2013
Accepted
23 Dec 2013
First published
03 Jan 2014

Chem. Commun., 2014,50, 2324-2326

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A direct, versatile route to functionalized trialkoxysilanes

B. Quiclet-Sire, Y. Yanagisawa and S. Z. Zard, Chem. Commun., 2014, 50, 2324 DOI: 10.1039/C3CC48570F

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