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Issue 18, 2014
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A direct, versatile route to functionalized trialkoxysilanes

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Abstract

The peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkoxy vinylsilanes leads to functionalized trialkoxysilanes. Prior addition of the dithiocarbonates to an alkene before reaction with the vinylsilane can be used to increase the complexity of the final product.

Graphical abstract: A direct, versatile route to functionalized trialkoxysilanes

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Publication details

The article was received on 09 Nov 2013, accepted on 23 Dec 2013 and first published on 03 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC48570F
Citation: Chem. Commun., 2014,50, 2324-2326
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    A direct, versatile route to functionalized trialkoxysilanes

    B. Quiclet-Sire, Y. Yanagisawa and S. Z. Zard, Chem. Commun., 2014, 50, 2324
    DOI: 10.1039/C3CC48570F

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