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Issue 16, 2014
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A significant enhancement of catalytic activities in oxidation with H2O2 over the TS-1 zeolite by adjusting the catalyst wettability

Liang Wang,a  Jing Sun,b  Xiangju Meng,*a  Weiping Zhang,c  Jian Zhang,a  Shuxiang Pan,a  Zhe Shena  and  Feng-Shou Xiao*a 
Author affiliations

* Corresponding authors

a Key Laboratory of Applied Chemistry of Zhejiang Province, Zhejiang University, Hangzhou 310028, China
E-mail: fsxiao@zju.edu.cn, mengxj@zju.edu.cn

b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

c State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China

Abstract

Hydrophilic TS-1 (H-TS-1) with rich hydroxyl groups, which were confirmed by 29Si and 1H NMR techniques, exhibits much higher activities in the oxidation than conventional TS-1. This phenomenon is strongly related to the unique features of high enrichment of H2O2 on H-TS-1.

Graphical abstract: A significant enhancement of catalytic activities in oxidation with H2O2 over the TS-1 zeolite by adjusting the catalyst wettability

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Publication details

The article was received on 27 Oct 2013, accepted on 09 Dec 2013 and first published on 09 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC48220K
Citation: Chem. Commun., 2014,50, 2012-2014
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    A significant enhancement of catalytic activities in oxidation with H2O2 over the TS-1 zeolite by adjusting the catalyst wettability

    L. Wang, J. Sun, X. Meng, W. Zhang, J. Zhang, S. Pan, Z. Shen and F. Xiao, Chem. Commun., 2014, 50, 2012
    DOI: 10.1039/C3CC48220K

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