Issue 9, 2014
From the journal:

Chemical Communications

Highly proton conductive nanoporous coordination polymers with sulfonic acid groups on the pore surface†

Padmini Ramaswamy,a   Ryotaro Matsuda,*a   Wataru Kosaka,a   George Akiyama,a   Hyung Joon Jeona  and  Susumu Kitagawa*ab  

* Corresponding authors

a Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan
E-mail: rmatsuda@icems.kyoto-u.ac.jp
Fax: +81-75-383-2103
Tel: +81-75-383-2103

b Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

Three new sulfonated porous coordination polymers (PCPs)/metal–organic frameworks (MOFs) have been synthesized using solvothermal methods. These PCPs possess porous structures with non-coordinating sulfonic acid groups or sulfonate with dimethyl ammonium cations and exhibit high proton conductivity at a low humidity of 60% RH (relative humidity) at ambient temperature.

Graphical abstract: Highly proton conductive nanoporous coordination polymers with sulfonic acid groups on the pore surface

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Article information

DOI
https://doi.org/10.1039/C3CC47980C
Article type
Communication
Submitted
17 Oct 2013
Accepted
21 Nov 2013
First published
10 Dec 2013

Chem. Commun., 2014,50, 1144-1146

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Highly proton conductive nanoporous coordination polymers with sulfonic acid groups on the pore surface

P. Ramaswamy, R. Matsuda, W. Kosaka, G. Akiyama, H. J. Jeon and S. Kitagawa, Chem. Commun., 2014, 50, 1144 DOI: 10.1039/C3CC47980C

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