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Issue 98, 2014
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Solid-solid phase interconversion in an organic conductor crystal: hydrogen-bond-mediated dynamic changes in π-stacked molecular arrangement and physical properties

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Abstract

Solid–solid phase interconversion was observed in an organic conductor based on a hydrogen-bonded (H-bonded) TTF (tetrathiafulvalene) molecular unit, in which the π-stacked molecular arrangement and physical properties were dynamically changed with unexpected transformation of the H-bond unit between the planar and bent forms.

Graphical abstract: Solid-solid phase interconversion in an organic conductor crystal: hydrogen-bond-mediated dynamic changes in π-stacked molecular arrangement and physical properties

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Publication details

The article was received on 03 Oct 2014, accepted on 21 Oct 2014 and first published on 23 Oct 2014


Article type: Communication
DOI: 10.1039/C4CC07810A
Citation: Chem. Commun., 2014,50, 15557-15560
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    Solid-solid phase interconversion in an organic conductor crystal: hydrogen-bond-mediated dynamic changes in π-stacked molecular arrangement and physical properties

    J. Yoshida, A. Ueda, A. Nakao, R. Kumai, H. Nakao, Y. Murakami and H. Mori, Chem. Commun., 2014, 50, 15557
    DOI: 10.1039/C4CC07810A

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