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Issue 95, 2014
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The solvent effect in an axially symmetric FeIII4 single-molecule magnet

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Abstract

A pair of enantiopure FeIII4 SMMs with axial symmetry was synthesized and characterized by magnetization and high-frequency electron paramagnetic resonance methods. The results reveal that the axial symmetry of the structure is broken by the interaction of FeIII4 with the disordered solvent molecules.

Graphical abstract: The solvent effect in an axially symmetric FeIII4 single-molecule magnet

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Publication details

The article was received on 25 Sep 2014, accepted on 13 Oct 2014 and first published on 13 Oct 2014


Article type: Communication
DOI: 10.1039/C4CC07580C
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 15090-15093
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    The solvent effect in an axially symmetric FeIII4 single-molecule magnet

    Y. Zhu, T. Yin, S. Jiang, A. Barra, W. Wernsdorfer, P. Neugebauer, R. Marx, M. Dörfel, B. Wang, Z. Wu, J. V. Slageren and S. Gao, Chem. Commun., 2014, 50, 15090
    DOI: 10.1039/C4CC07580C

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