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Issue 95, 2014
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Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

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Abstract

Tetraazaporphyrin (TAP) complexes with group 15 elements (phosphorus(V) or arsenic(V)) containing two axial OH ligands showed reversible spectroscopic changes with acid or base doping. Spectroscopic and theoretical analysis revealed that the modification of axial ligands can tune the interaction between peripheral substituents and the TAP macrocycle.

Graphical abstract: Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

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Publication details

The article was received on 19 Sep 2014, accepted on 10 Oct 2014 and first published on 21 Oct 2014


Article type: Communication
DOI: 10.1039/C4CC07408D
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 15101-15104
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    Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

    T. Furuyama, M. Asai and N. Kobayashi, Chem. Commun., 2014, 50, 15101
    DOI: 10.1039/C4CC07408D

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