Issue 95, 2014
From the journal:

Chemical Communications

Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands†

Taniyuki Furuyama,a   Mitsuo Asaia  and  Nagao Kobayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
E-mail: nagaok@m.tohoku.ac.jp
Tel: +81 22 795 7719

Abstract

Tetraazaporphyrin (TAP) complexes with group 15 elements (phosphorus(V) or arsenic(V)) containing two axial OH ligands showed reversible spectroscopic changes with acid or base doping. Spectroscopic and theoretical analysis revealed that the modification of axial ligands can tune the interaction between peripheral substituents and the TAP macrocycle.

Graphical abstract: Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

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Article information

DOI
https://doi.org/10.1039/C4CC07408D
Article type
Communication
Submitted
19 Sep 2014
Accepted
10 Oct 2014
First published
21 Oct 2014

Chem. Commun., 2014,50, 15101-15104

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Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

T. Furuyama, M. Asai and N. Kobayashi, Chem. Commun., 2014, 50, 15101 DOI: 10.1039/C4CC07408D

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