Issue 96, 2014
From the journal:

Chemical Communications

Magnetic blocking in extended metal atom chains: a pentachromium(ii) complex behaving as a single-molecule magnet†

A. Cornia,*a   L. Rigamonti,a   S. Boccedi,a   R. Clérac,bc   M. Rouzièresbc  and  L. Soraced  

* Corresponding authors

a Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Modena e Reggio Emilia & INSTM RU of Modena and Reggio Emilia, via G. Campi 183, 41125 Modena, Italy
E-mail: acornia@unimore.it

b CNRS, CRPP, UPR 8641, F-33600 Pessac, France

c Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France

d Laboratory of Molecular Magnetism (LaMM), Dipartimento di Chimica ‘Ugo Schiff’, Università degli Studi di Firenze & INSTM RU of Firenze, via della Lastruccia 3-13, 50019 Sesto Fiorentino (FI), Italy

Abstract

Compound [Cr5(tpda)4Cl2] (H2tpda = N2,N6-di(pyridin-2-yl)pyridine-2,6-diamine), an Extended Metal Atom Chain complex featuring two quadruply-bonded {Cr2} units, exhibits field-induced slow relaxation of its magnetization arising from the terminal chromium(II) ion and provides the first example of a chromium(II)-based Single-Molecule Magnet.

Graphical abstract: Magnetic blocking in extended metal atom chains: a pentachromium(ii) complex behaving as a single-molecule magnet

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Article information

DOI
https://doi.org/10.1039/C4CC06693F
Article type
Communication
Submitted
25 Aug 2014
Accepted
08 Oct 2014
First published
09 Oct 2014
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2014,50, 15191-15194

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Magnetic blocking in extended metal atom chains: a pentachromium(II) complex behaving as a single-molecule magnet

A. Cornia, L. Rigamonti, S. Boccedi, R. Clérac, M. Rouzières and L. Sorace, Chem. Commun., 2014, 50, 15191 DOI: 10.1039/C4CC06693F

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