Jump to main content
Jump to site search

Issue 88, 2014
Previous Article Next Article

Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface

Author affiliations

Abstract

Monolayer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid–graphite interface. Thermodynamical insights are obtained from an adapted Born–Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.

Graphical abstract: Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface

Back to tab navigation

Supplementary files

Publication details

The article was received on 09 Aug 2014, accepted on 08 Sep 2014 and first published on 09 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC06251E
Author version
available:
Download author version (PDF)
Citation: Chem. Commun., 2014,50, 13465-13468
  •   Request permissions

    Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface

    W. Song, N. Martsinovich, W. M. Heckl and M. Lackinger, Chem. Commun., 2014, 50, 13465
    DOI: 10.1039/C4CC06251E

Search articles by author

Spotlight

Advertisements