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[FeIII(TF4DMAP)OTf] catalysed anti-Markovnikov oxidation of terminal aryl alkenes to aldehydes and transformation of methyl aryl tertiary amines to formamides with H2O2 as a terminal oxidant

Yi-Dan Du,a   Chun-Wai Tse,b   Zhen-Jiang Xu,*a   Yungen Liub and   Chi-Ming Che*ab  
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a
Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China
E-mail: xuzhenjiang@mail.sioc.ac.cn
b
Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China
E-mail: cmche@hku.hk;
Fax: +852-2857-1586 ;
Tel: +852-2859-2154
Chem. Commun., 2014,50, 12669-12672

DOI: 10.1039/C4CC05972G
Received 31 Jul 2014, Accepted 22 Aug 2014
First published online 26 Aug 2014
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