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Issue 80, 2014
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An ultrastable {Ag55Mo6} nanocluster with a Ag-centered multishell structure

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Abstract

An ultrastable [Ag55(MoO4)6]43+ ({Ag55Mo6} for short) nanocluster with a Ag-centered multishell structure in compound [Ag55(MoO4)6(C[triple bond, length as m-dash]CtBu)24(CH3COO)18](OAc)·2H2O (1) has been obtained. The ultrastability of 1 was demonstrated by Mulliken population analysis. In addition, the potential wide gap semiconductor property and electrochemical properties of 1 were investigated.

Graphical abstract: An ultrastable {Ag55Mo6} nanocluster with a Ag-centered multishell structure

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Publication details

The article was received on 29 Jul 2014, accepted on 13 Aug 2014 and first published on 13 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC05893C
Citation: Chem. Commun., 2014,50, 11934-11937
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    An ultrastable {Ag55Mo6} nanocluster with a Ag-centered multishell structure

    K. Zhou, Y. Geng, L. Yan, X. Wang, X. Liu, G. Shan, K. Shao, Z. Su and Y. Yu, Chem. Commun., 2014, 50, 11934
    DOI: 10.1039/C4CC05893C

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