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Issue 92, 2014
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I2-catalyzed oxidative C(sp3)–H/S–H coupling: utilizing alkanes and mercaptans as the nucleophiles

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Abstract

By using alkanes and mercaptans as the nucleophiles with di-tert-butyl peroxide (DTBP) as the oxidant, I2-catalyzed oxidative C(sp3)–H/S–H coupling was achieved. This protocol provides a novel process to construct C(sp3)–S bonds from commercially available hydrocarbons and mercaptans.

Graphical abstract: I2-catalyzed oxidative C(sp3)–H/S–H coupling: utilizing alkanes and mercaptans as the nucleophiles

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Publication details

The article was received on 22 Jul 2014, accepted on 20 Sep 2014 and first published on 26 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC05661B
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 14386-14389
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    I2-catalyzed oxidative C(sp3)–H/S–H coupling: utilizing alkanes and mercaptans as the nucleophiles

    J. Yuan, X. Ma, H. Yi, C. Liu and A. Lei, Chem. Commun., 2014, 50, 14386
    DOI: 10.1039/C4CC05661B

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