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Issue 83, 2014
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Freezing-induced ordering of block copolymer micelles

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Abstract

We demonstrate here the ordering of block copolymer micelles by ice templating, below 0 °C. We used this for the preparation of silica monoliths that present an ice-templated macroporosity, combined with a 2D hexagonal mesostructure templated by the addition of P123. We propose a mechanism triggered by the progressive freezing-induced concentration.

Graphical abstract: Freezing-induced ordering of block copolymer micelles

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Publication details

The article was received on 22 Jul 2014, accepted on 29 Aug 2014 and first published on 29 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC05556J
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Citation: Chem. Commun., 2014,50, 12572-12574
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    Freezing-induced ordering of block copolymer micelles

    J. Dhainaut, G. Piana, S. Deville, C. Guizard and M. Klotz, Chem. Commun., 2014, 50, 12572
    DOI: 10.1039/C4CC05556J

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