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Issue 82, 2014
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Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324

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Abstract

Investigation of Croton insularis afforded the first in class seco-casbane diterpene, EBC-329. A highly oxidised casbane, EBC-324, was also isolated. The structural motif within EBC-324, which consists of an epoxidised hemi-acetal endoperoxide, is new to the casbane family.

Graphical abstract: Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324

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Publication details

The article was received on 14 Jul 2014, accepted on 13 Aug 2014 and first published on 02 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC05413J
Citation: Chem. Commun., 2014,50, 12315-12317
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    Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324

    L. A. Maslovskaya, A. I. Savchenko, E. H. Krenske, V. A. Gordon, P. W. Reddell, C. J. Pierce, P. G. Parsons and C. M. Williams, Chem. Commun., 2014, 50, 12315
    DOI: 10.1039/C4CC05413J

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