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Issue 81, 2014
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Modulating H2 sorption in metal–organic frameworks via ordered functional groups

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Abstract

Herein, we present the use of presynthetic and postsynthetic modification (PSM) approaches to regulate the structural organization of functional groups in the pores of isoreticular metal–organic frameworks (IRMOFs). It has been found that the structural ordering of aryl groups within the IRMOF pores results in hysteretic H2 sorption, while the same aryl groups introduced in a disordered manner displays reversible H2 sorption that is more typical of the IRMOF family.

Graphical abstract: Modulating H2 sorption in metal–organic frameworks via ordered functional groups

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Publication details

The article was received on 10 Jul 2014, accepted on 19 Aug 2014 and first published on 20 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC05265J
Citation: Chem. Commun., 2014,50, 12154-12157
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    Modulating H2 sorption in metal–organic frameworks via ordered functional groups

    P. V. Dau and S. M. Cohen, Chem. Commun., 2014, 50, 12154
    DOI: 10.1039/C4CC05265J

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