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Issue 78, 2014
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Study of the interaction of water with the aqua-soluble dimeric complex [RuCp(PTA)2–μ-CN–1κC:2κ2N-RuCp(PTA)2](CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane) by neutron and X-ray diffraction in solution

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Abstract

The study of an aqueous solution of [RuCp(PTA)2–μ-CN–1κC:2κ2N-RuCp(PTA)2](CF3SO3) by neutron and X-ray diffraction revealed surprising details as to how the water molecules interact with the complex and affect its properties. The present communication demonstrates the applicability of sophisticated scattering techniques in combination with theoretical calculations to the study of coordination compounds in aqueous solution.

Graphical abstract: Study of the interaction of water with the aqua-soluble dimeric complex [RuCp(PTA)2–μ-CN–1κC:2κ2N-RuCp(PTA)2](CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane) by neutron and X-ray diffraction in solution

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Publication details

The article was received on 07 Jul 2014, accepted on 04 Aug 2014 and first published on 20 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC05225K
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 11587-11590
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    Study of the interaction of water with the aqua-soluble dimeric complex [RuCp(PTA)2–μ-CN–1κC:2κ2N-RuCp(PTA)2](CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane) by neutron and X-ray diffraction in solution

    M. Serrano-Ruiz, S. Imberti, L. Bernasconi, N. Jadagayeva, F. Scalambra and A. Romerosa, Chem. Commun., 2014, 50, 11587
    DOI: 10.1039/C4CC05225K

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