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Issue 76, 2014
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Interfacial hydrogenation and deamination of nitriles to selectively synthesize tertiary amines

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Abstract

A novel one-pot method has been developed for the interfacial hydrogenation of nitriles to synthesize asymmetrical tertiary amines. The active Pt NWs allow for the preparation of a series of tertiary amines in excellent yields (up to 99.0%) and a mixed solvent is vital for the adjustment of the yield. And also, the reaction proceeded under mild conditions and is environmentally friendly.

Graphical abstract: Interfacial hydrogenation and deamination of nitriles to selectively synthesize tertiary amines

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Publication details

The article was received on 04 Jul 2014, accepted on 30 Jul 2014 and first published on 30 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC05132G
Citation: Chem. Commun., 2014,50, 11110-11113
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    Interfacial hydrogenation and deamination of nitriles to selectively synthesize tertiary amines

    S. Lu, C. Li, J. Wang, Y. Pan, X. Cao and H. Gu, Chem. Commun., 2014, 50, 11110
    DOI: 10.1039/C4CC05132G

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