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Formal [3+3] cycloaddition of indol-2-yl carbinol with azadiene and the oxidative ring expansion reaction for the synthesis of indole azepinones

Xue Zhong,ab   You Li,a   Jing Zhang,ab   Wu-Xia Zhang,ab   Shi-Xue Wanga and   Fu-She Han*ac  
Corresponding authors
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, China
The University of Chinese Academy of Sciences, Beijing 100864, China
Key Lab of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, CAS, Shanghai 200032, China
Chem. Commun., 2014,50, 11181-11184

DOI: 10.1039/C4CC04995K
Received 30 Jun 2014, Accepted 28 Jul 2014
First published online 31 Jul 2014
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