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Formal [3+3] cycloaddition of indol-2-yl carbinol with azadiene and the oxidative ring expansion reaction for the synthesis of indole azepinones

Xue Zhong,ab   You Li,a   Jing Zhang,ab   Wu-Xia Zhang,ab   Shi-Xue Wanga and   Fu-She Han*ac  
*
Corresponding authors
a
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, China
E-mail: fshan@ciac.ac.cn
b
The University of Chinese Academy of Sciences, Beijing 100864, China
c
Key Lab of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, CAS, Shanghai 200032, China
Chem. Commun., 2014,50, 11181-11184

DOI: 10.1039/C4CC04995K
Received 30 Jun 2014, Accepted 28 Jul 2014
First published online 31 Jul 2014
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