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Issue 74, 2014
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Copper-promoted oxidative-fluorination of arylphosphine under mild conditions

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Abstract

An efficient method for the synthesis of phosphoric fluoride via oxidative coupling between hydrophosphine oxide and NaF is reported. DDQ serves as the oxidizing reagent as well as the hydrogen acceptor. The process involves a Cu(II) catalysis and exhibits great functional group tolerance under mild reaction conditions.

Graphical abstract: Copper-promoted oxidative-fluorination of arylphosphine under mild conditions

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Publication details

The article was received on 25 Jun 2014, accepted on 25 Jul 2014 and first published on 28 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC04830J
Citation: Chem. Commun., 2014,50, 10879-10882
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    Copper-promoted oxidative-fluorination of arylphosphine under mild conditions

    N. Liu, L. Mao, B. Yang and S. Yang, Chem. Commun., 2014, 50, 10879
    DOI: 10.1039/C4CC04830J

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