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Issue 75, 2014
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Red-luminescent biphosphine stabilized ‘Cu12S6’ cluster molecules

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Abstract

The synthesis, molecular structures and luminescence properties of two ‘Cu12S6’ cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields (≥48%) and good stability towards oxygen.

Graphical abstract: Red-luminescent biphosphine stabilized ‘Cu12S6’ cluster molecules

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Publication details

The article was received on 20 Jun 2014, accepted on 27 Jul 2014, published on 30 Jul 2014 and first published online on 30 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC04702H
Citation: Chem. Commun., 2014,50, 11043-11045
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    Red-luminescent biphosphine stabilized ‘Cu12S6’ cluster molecules

    X. Yang, I. Issac, S. Lebedkin, M. Kühn, F. Weigend, D. Fenske, O. Fuhr and A. Eichhöfer, Chem. Commun., 2014, 50, 11043
    DOI: 10.1039/C4CC04702H

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