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Issue 80, 2014
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Cyclometalated gold(III) complexes for chemoselective cysteine modification via ligand controlled C–S bond-forming reductive elimination

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Abstract

Modular assembly of cyclometalated gold(III) complexes by choosing appropriate bidentate C,N-donor ligands and ancillary ligands for chemoselective cysteine modification of peptides and proteins via C–S bond-forming reductive elimination has been achieved.

Graphical abstract: Cyclometalated gold(iii) complexes for chemoselective cysteine modification via ligand controlled C–S bond-forming reductive elimination

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Publication details

The article was received on 12 Jun 2014, accepted on 18 Aug 2014 and first published on 18 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC04467C
Citation: Chem. Commun., 2014,50, 11899-11902
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    Cyclometalated gold(III) complexes for chemoselective cysteine modification via ligand controlled C–S bond-forming reductive elimination

    K. K. Kung, H. Ko, J. Cui, H. Chong, Y. Leung and M. Wong, Chem. Commun., 2014, 50, 11899
    DOI: 10.1039/C4CC04467C

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