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Issue 66, 2014
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Merging of inner and outer ruthenium organometallic coordination motifs within an azuliporphyrin framework

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Abstract

The insertion of ruthenium(II) into an azuliporphyrin (TPAP) has yielded carbonyl ruthenium(II) azuliporphyrin [Ru(TPAP)(CO)] featuring an equatorial CNNN set of donors. Its azulene moiety serves as the π-coordination platform to accommodate the Ru4(CO)9 cluster. This chemistry proved to be general giving rise to a series of bimetallic complexes [M(TPAP){Ru4(CO)9}] (M = Ru(CO), Ni, Pd, Pt).

Graphical abstract: Merging of inner and outer ruthenium organometallic coordination motifs within an azuliporphyrin framework

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Publication details

The article was received on 04 Jun 2014, accepted on 28 Jun 2014 and first published on 30 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC04271A
Citation: Chem. Commun., 2014,50, 9270-9272
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    Merging of inner and outer ruthenium organometallic coordination motifs within an azuliporphyrin framework

    M. J. Białek and L. Latos-Grażyński, Chem. Commun., 2014, 50, 9270
    DOI: 10.1039/C4CC04271A

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