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Issue 66, 2014
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Nitrogen-centered radical-mediated C–H imidation of arenes and heteroarenes via visible light induced photocatalysis

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Abstract

The C–H imidation of arenes and heteroarenes has been achieved via visible light induced photocatalysis. In the presence of an iridium(III) photoredox catalyst, the reaction of aromatic substrates with N-chlorophthalimide furnishes the N-aryl products at room temperature through a nitrogen-centered radical mediated aromatic substitution.

Graphical abstract: Nitrogen-centered radical-mediated C–H imidation of arenes and heteroarenes via visible light induced photocatalysis

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Publication details

The article was received on 21 May 2014, accepted on 01 Jul 2014 and first published on 01 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC03905J
Citation: Chem. Commun., 2014,50, 9273-9276
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    Nitrogen-centered radical-mediated C–H imidation of arenes and heteroarenes via visible light induced photocatalysis

    H. Kim, T. Kim, D. G. Lee, S. W. Roh and C. Lee, Chem. Commun., 2014, 50, 9273
    DOI: 10.1039/C4CC03905J

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