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Issue 70, 2014
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A zirconium squarate metal–organic framework with modulator-dependent molecular sieving properties

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Abstract

We report the first zirconium metal–organic framework based on squaric acid, representing the member with the smallest unit cell in the isoreticular UiO-66 family. Its molecular sieving properties are strongly influenced by the monocarboxylic acid modulator incorporated during synthesis.

Graphical abstract: A zirconium squarate metal–organic framework with modulator-dependent molecular sieving properties

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Publication details

The article was received on 16 May 2014, accepted on 11 Jul 2014 and first published on 11 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC03764B
Citation: Chem. Commun., 2014,50, 10055-10058
  • Open access: Creative Commons BY license
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    A zirconium squarate metal–organic framework with modulator-dependent molecular sieving properties

    B. Bueken, H. Reinsch, N. Reimer, I. Stassen, F. Vermoortele, R. Ameloot, N. Stock, C. E. A. Kirschhock and D. De Vos, Chem. Commun., 2014, 50, 10055
    DOI: 10.1039/C4CC03764B

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