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Issue 69, 2014
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Convergent and divergent two-dimensional coordination networks formed through substrate-activated or quenched alkynyl ligation

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Abstract

Metal coordination assemblies of the symmetric bi-functional 4,4′-di-(1,4-buta-1,3-diynyl)-benzoic acid are investigated by scanning tunnelling microscopy on metal surfaces. The formation of long-range ordered, short-range disordered and random phases depends on the competition between the convergent and divergent coordination motifs of the individual functional groups and is crucially influenced by the substrate.

Graphical abstract: Convergent and divergent two-dimensional coordination networks formed through substrate-activated or quenched alkynyl ligation

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Publication details

The article was received on 15 May 2014, accepted on 11 Jul 2014 and first published on 11 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC03723E
Citation: Chem. Commun., 2014,50, 9973-9976
  • Open access: Creative Commons BY license
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    Convergent and divergent two-dimensional coordination networks formed through substrate-activated or quenched alkynyl ligation

    J. Čechal, C. S. Kley, T. Kumagai, F. Schramm, M. Ruben, S. Stepanow and K. Kern, Chem. Commun., 2014, 50, 9973
    DOI: 10.1039/C4CC03723E

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