Issue 68, 2014
From the journal:

Chemical Communications

Initiator-chain transfer agent combo in the RAFT polymerization of styrene†

Ying Wu,a   Wei Zhang,a   Zhengbiao Zhang,a   Xiangqiang Pan,a   Zhenping Cheng,a   Jian Zhu*a  and  Xiulin Zhu*a  

* Corresponding authors

a Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, P. R. China
E-mail: chemzhujian@suda.edu.cn, xlzhu@suda.edu.cn

Abstract

The combo agent with roles of initiator and chain transfer agent was demonstrated in RAFT polymerization of styrene. Polymers with defined structures at both α and ω ends were obtained, which was verified by the successful synthesis of seven-block segments of PS and PMA by sequential addition of monomers in one pot.

Graphical abstract: Initiator-chain transfer agent combo in the RAFT polymerization of styrene

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Article information

DOI
https://doi.org/10.1039/C4CC03699A
Article type
Communication
Submitted
15 May 2014
Accepted
01 Jul 2014
First published
01 Jul 2014

Chem. Commun., 2014,50, 9722-9724

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Initiator-chain transfer agent combo in the RAFT polymerization of styrene

Y. Wu, W. Zhang, Z. Zhang, X. Pan, Z. Cheng, J. Zhu and X. Zhu, Chem. Commun., 2014, 50, 9722 DOI: 10.1039/C4CC03699A

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