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Issue 70, 2014
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Nanoscale insight into C–C coupling on cobalt nanoparticles

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Abstract

The Ullmann coupling of bromobenzene to biphenyl on Co nanoparticles proceeds below room temperature via an intermediate in which phenyl groups are bound directly to metallic Co. A similar surface-bound benzyl intermediate is observed for coupling of benzylbromide to bibenzyl on Co.

Graphical abstract: Nanoscale insight into C–C coupling on cobalt nanoparticles

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Publication details

The article was received on 14 May 2014, accepted on 13 Jul 2014 and first published on 14 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC03678F
Citation: Chem. Commun., 2014,50, 10035-10037
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    Nanoscale insight into C–C coupling on cobalt nanoparticles

    E. A. Lewis, C. J. Murphy, A. Pronschinske, M. L. Liriano and E. C. H. Sykes, Chem. Commun., 2014, 50, 10035
    DOI: 10.1039/C4CC03678F

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