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Issue 86, 2014
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Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide

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Abstract

The cobalt-catalyzed carboxylation of propargyl acetates with CO2 (1 atm) is described. The reaction proceeds at room temperature in the presence of Mn powder as a reducing reagent. Various propargyl acetates are converted to the corresponding carboxylic acids in good to high yields.

Graphical abstract: Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide

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Publication details

The article was received on 14 May 2014, accepted on 05 Jun 2014 and first published on 05 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC03644A
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 13052-13055
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    Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide

    K. Nogi, T. Fujihara, J. Terao and Y. Tsuji, Chem. Commun., 2014, 50, 13052
    DOI: 10.1039/C4CC03644A

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